Course title
無機化学Ⅱ   [Inorganic Chemistry Ⅱ]
Course category technology speciality courses,ets.  Requirement   Credit 2 
Department   Year 24  Semester Spring 
Course type Spring  Course code 022207
Instructor(s)
齋藤 守弘   [SAITO Morihiro]
Facility affiliation Faculty of Engineering Office   Email address

Course description
Inorganic chemistry II will mainly deal with the field of coordination chemistry. The lecture will give the basic knowledge on coordination compounds (kinds, nomenclature and functional properties) and their reaction mechanisms. Fundamental theory (ligand field theory) and new fields of coordination chemistry (organometallic and bioinorganic chemistry) will be also introduced and explained by using some practical examples.
Expected Learning
1. Understanding on the concept of coordination chemistry.
2. Acquiring the knowledge on kinds, nomenclature, special effects, reaction mechanisms and new-developed fields of coordination compounds.
Course schedule
Week1 Guidance, review of chemical bond from the view of quantum chemistry
Week2 Introduction of coordination chemistry
Week3 Coordination compounds, coordination number and structures, ligands
Week4 Optical isomer, ionization, linkage and coordination isomerisms
Week5 Nomenclature of complexes
Week6 Stability of metal complexes, stepwise and overall formation constants
Week7 Chelate effect, reactivity of coordination compounds, anation, aquation
Week8 Midterm examination
Week9 Ligand field theory, crystal field theory, molecular orbital theory
Week10 High-spin and low-spin complexes, magnetism
Week11 Electronic absorption spectra, d-d, CT and π-π* transitions
Week12 Jahn-Teller effect, ligand field stabilization energy (LFSE), Irving-Williams series of stability
Week13 Organometallic chemistry; eighteen electron rule, CO ligand, back-donation
Week14 Bioinorganic chemistry; metalloenzyme (hemoglobin), coenzyme (vitamin B12), photosynthesis (chlorophyll)
Week15 Terminal examination
Prerequisites
Required Text(s) and Materials
Inorganic Chemistry Fourth Edition, Tokyo Kagaku Dojin
References
Assessment/Grading
Attendance, attitude in lecture including questions, mini test, midterm and terminal examinations
Message from instructor(s)
Course keywords
Coordination chemistry, coordination number and structures, ligands, optical isomer, ionization, linkage and coordination isomerism, nomenclature, ligand field theory, crystal field theory, high-spin and low-spin complexes, magnetism, electronic absorption spectra, organometallic chemistry, bioinorganic chemistry
Office hours
Remarks 1
Remarks 2
Related URL
Lecture Language
Japanese
Language Subject
Last update
3/19/2017 6:11:24 PM