| Course title | |||||
| 反応速度論 [Kinetics] | |||||
| Course category | technology speciality courses,ets. | Requirement | Credit | 2 | |
| Department | Year | 2～4 | Semester | Fall | |
| Course type | Fall | Course code | 022220 | ||
| Instructor(s) | |||||
| 森 啓二 [MORI Keiji] | |||||
| Facility affiliation | Faculty of Engineering | Office | Email address | ||
| Course description |
| Chemical kinetics (reaction kinetics), which is the study quantitatively and/or theoretically dealing with rate of chemical processes, provides a useful methodology for understanding and elucidating a reaction mechanism. This lecture gives an explanation for the definition of reaction rates, reaction rate laws, reaction mechanisms and so on. |
| Expected Learning |
|
1) Participants can solve a reaction rate equation using a differential equation. 2) Participants can give an explanation for the reaction mechanism using the concept of the kinetics. |
| Course schedule |
|
1st Lecture: Explanation of the present lecture, and Introduction to the present lecture (Experimental procedure for the investigation of the kinetics, Concepts of kinetic and thermodynamic control, textbook chap.22, pp847-852) 2nd Lecture: Definition of reaction rates (Rate equation, Rate constant, Reaction order, textbook chap.22, pp852-857) 3rd Lecture: Integral rate equation (First order reaction, Second order reaction, Half-life period, textbook chap.22, pp857-861) 4th Lecture: Near-equilibrium reaction, and Temperature dependency of the reaction rate (Relaxation method, and Arrhenius equation, textbook chap.22, pp862-868) 5th Lecture: Elementary process and consecutive reaction (Pre-equilibrium, Steady-state approximation, Rate-determining step, textbook chap.22, pp868-874) 6th Lecture: Homogeneous catalysis (Enzyme, Michelis-Menten mechanism, textbook chap.23, pp899-905) 7th Lecture: Unimolecular reaction (Lindemann-Hinshelwood mechanism, textbook chap.22, pp878-881) and Chain reaction (textbook chap.23, pp890-893) 8th Lecture: Midterm test (The contents of 2nd?7th lectures are on the test) 9th Lecture: Kinetics of explosion and polymerization (textbook chap.23, pp893-899) 10th Lecture: Collision theory and Kinetic Theory of Gases (textbook chap.24, pp932-937, chap.21, pp804-813) 11th Lecture: Molecular motion in solution, and Diffusion (textbook chap.21, pp813-839) 12th Lecture: Diffusion-controlled reaction, and Activated complex theory (Eyring equation, textbook chap.24, pp937-947) 13th Lecture: Adsorption degree (Physisorption and chemisorption, Rate of adsorption, Surface process, textbook chap.25, pp979-990) 14th Lecture: Homogeneous catalysis (Catalysis on the surface, textbook chap.25, pp990-996) 15th Lecture: Final test (The contents of all lectures are on the test) |
| Prerequisites |
| Participants should take “Calculus”, “Physical Chemistry I”, and “Physical Chemistry II”. |
| Required Text(s) and Materials |
| Atkins' Physical Chemistry (Japanese version, 8ED, volume two) translated by H. Chihara, N. Nakamura, Tokyo Kagaku Dojin Ltd. Co. |
| References |
| Assessment/Grading |
| Midterm test (50%), Final test (50%) |
| Message from instructor(s) |
| Participants should acquire the method for solving basic differential equations, which are frequently used in this lecture. Participants should carry out a review by use of practice problems given in the lecture. |
| Course keywords |
| Kinetics, reaction rate, reaction rate law, reaction mechanism, |
| Office hours |
| None specified (Office：BuildingNew No.1, Room 510A) |
| Remarks 1 |
| Remarks 2 |
| Related URL |
| Lecture Language |
| Japanese |
| Language Subject |
| Last update |
| 3/2/2017 10:11:00 AM |