| Course title | |||||
| 有機化学基礎 [Fundamental Organic Chemistry] | |||||
| Course category | technology speciality courses,ets. | Requirement | Credit | 2 | |
| Department | Year | 1～4 | Semester | Fall | |
| Course type | Fall | Course code | 021414 | ||
| Instructor(s) | |||||
| 飯島 淳 [IJIMA Jun] | |||||
| Facility affiliation | Graduate School of Engineering | Office | Email address | ||
| Course description |
| This course provides students with fundamentals of organic chemistry. After confirming the basis of organic compound, nomenclature, structure, properties, synthesis, reactivity of alkane, haloalkane, alcohol, ether, alkene, alkyne, and aromatic compound are lectured. Also, basic stereochemistry and the reaction mechanism using bent arrow are lectured. |
| Expected Learning |
| To acquire the basis of organic chemistry and to understand the synthesis and reactivity from the view point of the properties of functional groups. |
| Course schedule |
|
1. Guidance, Structure and bonding of organic compound Coulombic attraction, Bonding, Lewis structure, Resonance structure Atomic orbital and molecular orbital, Hybrid orbital 2. Structure of alkane Nomenclature, Structure and properties, Conformation, Potential energy 3. Reaction of alkane Radical, Hyperconjugation, Radical chain mechanism, Relative reactivity and selectivity 4. Cycloalkane Nomenclature, Properties, Ring strain and structure, cyclohexane and substituted cyclohexane 5. Stereoisomer Chiral molecule, optical activity, R, S nomenclature, Fischer projection, Diastereomer Meso compound, 6. Properties and reaction of haloalkane Nomenclature, Properties, Nucleophilic substitution reaction, Stereochemistry of SN2 reaction Leaving group ability, Nucleophilicity 7. Reaction of haloalkane SN1 reaction, E1 reaction, E2 reaction, Competition of elimination reaction with substitution 8. Midterm Exam 9. Hydroxyl group Nomenclature, Synthesis of alcohol, Organometallic reagent 10. Reaction of alcohol and chemistry of ether Synthesis of alkoxide, Substitution and elimination of alcohol, Rearrangement of carbocation 11. Structure of alkene Nomenclature, Structure and properties, Synthesis of alkene 12. Reaction of alkene Electrophilic addition, Markovnikov’s rule, Ozonolysis 13. Structure and reaction of circular sextet electronic system Nomenclature, Structure and resonance energy, Hucklel’s rule, Electrophilic substitution Friedel-Crafts reaction 14. Electrophilic attack to the benzene analogues Activation and inactivation of benzene ring by substituent, Orientation 15. Term Exam |
| Prerequisites |
| 「Basic Inorganic Chemistry」in Spring semester wish to be learned. |
| Required Text(s) and Materials |
| “Vollhardt ? Schore Organic Chemistry” by K. P. C. Vollhardt, N. E. Schore |
| References |
|
“McMurry Fundamentals of Organic Chemistry” by J. McMurry “McMurry Organic Chemistry” by J. McMurry “Basic Organic Chemistry” by K. Ohshima “Jones Organic Chemistry” by M. Jones, Jr., S. A. Fleming |
| Assessment/Grading |
| Attendance and daily test (20%) Midterm exam (40%) + Term exam (40%) |
| Message from instructor(s) |
| Based on the basic inorganic chemistry in Spring semester, basic organic chemistry is lectured. |
| Course keywords |
| Alkane, Haloalkane, Hydroxyl compound, Alkene, Alkyne, Aromatic compound |
| Office hours |
| Remarks 1 |
| Remarks 2 |
| Related URL |
| Lecture Language |
| Language Subject |
| Last update |
| 11/9/2018 10:36:19 AM |