| Course title | |||||
| 反応速度論 [Kinetics] | |||||
| Course category | technology speciality courses,ets. | Requirement | Credit | 2 | |
| Department | Year | 2～4 | Semester | Spring | |
| Course type | Spring | Course code | 022410 | ||
| Instructor(s) | |||||
| 稲澤 晋 [INASAWA Susumu] | |||||
| Facility affiliation | Graduate School of Bio-Applications and Systems Engineering | Office | Email address | ||
| Course description |
| Chemical reactions are frequently used in industry. We need to understand reaction kinetics, such as reaction rate, to properly control chemical reactions. In this lecture, several topics, from fundamentals to applications, are introduced. Students are expected to derive equation sets of chemical reactions and to understand reaction kinetics. |
| Expected Learning |
|
・Derivation of a set of equations related to reaction rates. ・Understanding the meaning of reaction rate constants. ・Derivation of analytical solution using an approximation such as quasi-steady state approximation. ・Understanding and explaining of chemical reactions based on equations of reaction rates. |
| Course schedule |
|
The content might be changed depending upon your understanding. Week 1: Introduction (significance of kinetics), Definition of kinetics, First-order reaction(1) Week 2: First order reaction(2), second-order reaction, half-time, equilibrium Week 3: Temperature dependence, elemental reactions, consecutive reactions, rate-determining step(1) Week 4: Rate-determining step(2), steady-state approximation, pre-equilibrium, Michaelis-Menten mechanism(1) Week 5: Practice Week 6: Michaelis-Menten mechanism(2), unimolecular reactions (Hindermann-Hinshelwood mechanism) Week 7: Midterm exam Week 8: Chain reactions, chain-branching explosion Week 9: Thermal explosion, stepwise polymerization kinetics Week 10: Chain polymerization kinetics, homogeneous catalyst Week 11: Molecules in motion (Collision frequency, mean free path) Week 12: Adsorption and desorption kinetics, Langmuir isotherm Week 13: Heterogeneous catalyst, Langmuir-Hinshelwood mechanism Week 14: Summary Week 15: Final exam |
| Prerequisites |
| Thermodynamics |
| Required Text(s) and Materials |
| “Physical Chemistry eighth edition” by Peter Atkins, Julio de Paula (mainly Ch.22-25) |
| References |
| Assessment/Grading |
|
Midterm-exam (45%), final-exam (45%) and short exam in each lecture(10%) Criteria (Full score : 100): S: > 90, A: 80-89, B: 70-79, C: 60-69, D:< 59. You are not allowed to take exam if you are absent from 30% of lectures. |
| Message from instructor(s) |
| Course keywords |
| Reaction rate, reaction order, mechanism, elemental reaction, steady-state approximation |
| Office hours |
| Remarks 1 |
| Remarks 2 |
| Related URL |
| Lecture Language |
| Language Subject |
| Last update |
| 3/23/2018 4:15:46 PM |