Course title
無機化学Ⅱ   [Inorganic Chemistry Ⅱ]
Course category	technology speciality courses,ets.	Requirement		Credit	2
Department		Year	2～4	Semester	1st
Course type	1st	Course code	022207
Instructor(s)
岩間 悦郎   [IWAMA Etsuro]
Facility affiliation	Faculty of Engineering	Office		Email address

Course description

Inorganic chemistry II will mainly deal with the field of coordination chemistry. The lecture will give the basic knowledge on coordination compounds (kinds, nomenclature and functional properties) and their reaction mechanisms. Fundamental theory (ligand field theory) and new fields of coordination chemistry (organometallic and bioinorganic chemistry) will be also introduced and explained by using some practical examples.

Expected Learning

1. Understanding on the concept of coordination chemistry. 2. Acquiring the knowledge on kinds, nomenclature, special effects, reaction mechanisms and new-developed fields of coordination compounds.

Course schedule

Week1 Guidance, review of chemical bond from the view of quantum chemistry Week2 Introduction of coordination chemistry Week3 Coordination compounds, coordination number and structures, ligands Week4 Optical isomer, ionization, linkage and coordination isomerisms Week5 Nomenclature of complexes Week6 Stability of metal complexes, stepwise and overall formation constants Week7 Chelate effect, reactivity of coordination compounds, anation, aquation Week8 Midterm summary 　　　　Midterm examination Week9 Ligand field theory, crystal field theory, molecular orbital theory Week10 High-spin and low-spin complexes, magnetism Week11 Electronic absorption spectra, d-d, CT and π-π* transitions Week12 Jahn-Teller effect, ligand field stabilization energy (LFSE), Irving-Williams series of stability Week13 Organometallic chemistry; eighteen electron rule, CO ligand, back-donation Week14 Bioinorganic chemistry; metalloenzyme (hemoglobin), coenzyme (vitamin B12), photosynthesis (chlorophyll) Week15 Terminal summary Terminal examination

Prerequisites

Required Text(s) and Materials

Inorganic Chemistry Fourth Edition, Tokyo Kagaku Dojin

References

Assessment/Grading

Exercises (20%), mid-term test (40%), and terminal exam (40%)

Message from instructor(s)

Course keywords

Coordination chemistry, coordination number and structures, ligands, optical isomer, ionization, linkage and coordination isomerism, nomenclature, ligand field theory, crystal field theory, high-spin and low-spin complexes, magnetism, electronic absorption spectra, organometallic chemistry, bioinorganic chemistry

Office hours

Remarks 1

Remarks 2

Related URL

Lecture Language

Japanese

Language Subject

Last update

2/4/2020 8:21:47 PM