| Course title | |||||
| 反応速度論 [Kinetics] | |||||
| Course category | technology speciality courses,ets. | Requirement | Credit | 2 | |
| Department | Year | 2～4 | Semester | 3rd | |
| Course type | 3rd | Course code | 022220 | ||
| Instructor(s) | |||||
| 森 啓二 [MORI Keiji] | |||||
| Facility affiliation | Faculty of Engineering | Office | Email address | ||
| Course description |
| Chemical kinetics (reaction kinetics), which is the study quantitatively and/or theoretically dealing with rate of chemical processes, provides a useful methodology for understanding and elucidating a reaction mechanism. This lecture gives an explanation for the definition of reaction rates, reaction rate laws, reaction mechanisms and so on. Participants should take “Calculus”, “Physical Chemistry I”, and “Physical Chemistry II”. |
| Expected Learning |
|
1) Participants can solve a reaction rate equation using a differential equation. 2) Participants can give an explanation for the reaction mechanism using the concept of the kinetics. Corresponding criteria in the Diploma Policy: See the Curriculum maps. |
| Course schedule |
|
1st Lecture: Explanation of the present lecture, and Introduction to the present lecture (Experimental procedure for the investigation of the kinetics, Concepts of kinetic and thermodynamic control, textbook chap.22, pp847-852) 2nd Lecture: Definition of reaction rates (Rate equation, Rate constant, Reaction order, textbook chap.22, pp852-857) 3rd Lecture: Integral rate equation (First order reaction, Second order reaction, Half-life period, textbook chap.22, pp857-861) 4th Lecture: Near-equilibrium reaction, and Temperature dependency of the reaction rate (Relaxation method, and Arrhenius equation, textbook chap.22, pp862-868) 5th Lecture: Elementary process and consecutive reaction (Pre-equilibrium, Steady-state approximation, Rate-determining step, textbook chap.22, pp868-874) 6th Lecture: Homogeneous catalysis (Enzyme, Michelis-Menten mechanism, textbook chap.23, pp899-905) 7th Lecture: Unimolecular reaction (Lindemann-Hinshelwood mechanism, textbook chap.22, pp878-881) and Chain reaction (textbook chap.23, pp890-893) 8th Lecture: Summarization of the contents of 1st-7th lectures, Midterm test 9th Lecture: Kinetics of explosion and polymerization (textbook chap.23, pp893-899) 10th Lecture: Collision theory and Kinetic Theory of Gases (textbook chap.24, pp932-937, chap.21, pp804-813) 11th Lecture: Molecular motion in solution, and Diffusion (textbook chap.21, pp813-839) 12th Lecture: Diffusion-controlled reaction, and Activated complex theory (Eyring equation, textbook chap.24, pp937-947) 13th Lecture: Adsorption degree (Physisorption and chemisorption, Rate of adsorption, Surface process, textbook chap.25, pp979-990) 14th Lecture: Homogeneous catalysis (Catalysis on the surface, textbook chap.25, pp990-996) 15th Lecture: Summarization of the contents of 1st-14th lectures, final test |
| Prerequisites |
| Participants should take “Calculus”, “Physical Chemistry I”, and “Physical Chemistry II”. |
| Required Text(s) and Materials |
| Atkins' Physical Chemistry (Japanese version, 10ED, volume two) translated by H. Chihara, N. Nakamura, Tokyo Kagaku Dojin Ltd. Co. |
| References |
| Assessment/Grading |
| Midterm test (50%), Final test (50%) |
| Message from instructor(s) |
| Participants should acquire the method for solving basic differential equations, which are frequently used in this lecture. Participants should carry out a review by use of practice problems given in the lecture. |
| Course keywords |
| Kinetics, reaction rate, reaction rate law, reaction mechanism, |
| Office hours |
| Monday afternoon (Office：BuildingNew No.1, Room 510A) |
| Remarks 1 |
| Remarks 2 |
| Related URL |
| Lecture Language |
| Japanese |
| Language Subject |
| Last update |
| 3/15/2019 2:49:03 PM |