Course title
反応速度論   [Kinetics]
Course category technology speciality courses,ets.  Requirement   Credit 2 
Department   Year 24  Semester 1st 
Course type 1st  Course code 022410
Instructor(s)
稲澤 晋   [INASAWA Susumu]
Facility affiliation Graduate School of Bio-Applications and Systems Engineering Office   Email address

Course description
Chemical reactions are frequently used in industry. We need to understand reaction kinetics, such as reaction rate, to properly control chemical reactions. In this lecture, several topics, from fundamentals to applications, are introduced. Students are expected to derive equation sets of chemical reactions and to understand reaction kinetics.
Expected Learning
・Derivation of a set of equations related to reaction rates.
・Understanding the meaning of reaction rate constants.
・Derivation of analytical solution using an approximation such as quasi-steady state approximation.
・Understanding and explaining of chemical reactions based on equations of reaction rates.

Corresponding criteria in the Diploma Policy:
See the Curriculum maps.
Course schedule
The content might be changed depending upon your understanding.

Week 1: Introduction (significance of kinetics), Definition of kinetics, First-order reaction(1)
Week 2: First order reaction(2), second-order reaction, half-time, equilibrium
Week 3: Temperature dependence, elemental reactions, consecutive reactions, rate-determining step(1)
Week 4: Rate-determining step(2), steady-state approximation, pre-equilibrium,
Week 5: Michaelis-Menten mechanism(1)
Week 6: Michaelis-Menten mechanism(2)
Week 7: Unimolecular reactions (Hindermann-Hinshelwood mechanism)
Week 8: Chain reactions, chain-branching explosion
Week 9: Thermal explosion, stepwise polymerization kinetics
Week 10: Chain polymerization kinetics, homogeneous catalyst
Week 11: Molecules in motion (Collision frequency, mean free path)
Week 12: Adsorption and desorption kinetics
Week 13: Langmuir isotherm
Week 14: Heterogeneous catalyst
Week 15: Langmuir-Hinshelwood mechanism
Prerequisites
Thermodynamics
Required Text(s) and Materials
“Physical Chemistry eighth edition” by Peter Atkins, Julio de Paula (mainly Ch.22-25)
References
Assessment/Grading
Midterm-exam (45%), final-exam (45%) and short exam in each lecture(10%)
Criteria (Full score : 100): S: > 90, A: 80-89, B: 70-79, C: 60-69, D:< 60.
You are not allowed to take exam if you are absent from 30% of lectures.
Message from instructor(s)
Course keywords
Reaction rate, reaction order, mechanism, elemental reaction, steady-state approximation
Office hours
Mon. 12:00-12:30
Remarks 1
Remarks 2
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Last update
2/27/2019 6:06:54 PM