| Course title | |||||
| 有機材料解析特論Ⅰ [Organic Materials Characterization I] | |||||
| Course category | courses for master's programs | Requirement | Credit | 2 | |
| Department | Year | ～ | Semester | 3rd | |
| Course type | 3rd | Course code | 1060213 | ||
| Instructor(s) | |||||
| 米澤 宣行, 臼井 博明 [YONEZAWA Noriyuki, USUI Hiroaki] | |||||
| Facility affiliation | Faculty of Engineering | Office | afjgxte/L1151 | Email address | |
| Course description |
|
The course requires the mid-term research report for the student's graduate course study on organic, polymer, and applied material chemistry with the analysis, expectation, scope. Presentation and discussion will be held. For the students planning to attend this course, please refer "Message from the instructor(s)". a. Learn about the transfer reaction and its basic related items, which are important areas of organic reaction chemistry that have not been dealt with in the organic chemistry related courses offered in the undergraduate course of the Department of Organic Materials Chemistry. Stanley H. Pine, Organic Chemistry 5th ed., McGraw-Hill Education; International (1987), Chapters 24, 27, 26 commented on reading and content. b. Try to understand the basic concepts of rearrangement reaction and its underlying radical reaction, organic photochemistry and organic electrochemistry, grasp outline of rearrangement reaction, and understand the contents of the related report of the journal while referring to the textbook Aim to acquire the power of the level. |
| Expected Learning |
|
Reaction pathways in the field of organic chemistry can be explained by means of organic electronic symbols and by molecular orbital theory for radical-light / electro-dislocation reactions (skills explaining the indicated reactions).View the diploma policy of this subject: Please refer to the curriculum map of the course guidance. |
| Course schedule |
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Basically, it will follow the textbook (English version). 1st to 5th: Chapter 26 (radical reaction), 6th to 11th: 27th chapter (organic photochemistry / organic electrochemistry), 12th to 15th: 26th chapter (rearrangement reaction), The basis of the first radical reaction History and characteristics of radical reactions Each theory of the 2-5th radical reaction Fragmentation, substitution, addition, oxidation, reduction The basis of the sixth organic light reaction Absorption of electromagnetic waves, excited states, photoreaction (chemical) processes, energy transfer and sensitization 7th-9th Aspects of Organic Photoreaction Photoreduction, photolysis, cycloaddition, isomerization and rearrangement, orbital symmetry and photochemical process, chemiluminescence 10th and 11th Basic Organic Electrical Reactions Basics of Organic Electrical Reactions and the Theory of Typical Organic Electrical Reactions 12th Rearrangement reaction (1) Rearrangement by transfer of atomic group to electron deficient carbon. ・ Relocation by transfer of atomic group to carbocatin . Mobility of moving group (group) and specificity in pinacol rearrangement ・ Stereochemistry of rearrangement ・ Relocation by transfer of atomic group to carbene 13th Rearrangement reaction (2) Rearrangement by transfer of atomic groups to electron deficient carbon. Part 2. ・ Relocation by transfer of atomic group to nitrogen atom ・ Relocation by transfer of atomic group to oxygen atom ・ Relocation by transfer of atomic group to boron atom ・ Relocation involving five-coordinate carbon atom (super strong acid, super electrophilic agent) 14th Rearrangement Reaction (3) Rearrangements involving free radicals (free radicals) and anionoids (anion equivalent species) ・ Rearrangement involving free radicals (free radicals) ・ Relocation involving anionoid (anion equivalent chemical species) 15th Rearrangement Reaction (4) Dislocations explained by orbital symmetry ・ Sigmatropic dislocation ・ Electronic cyclic reaction ・ Moebius-Huckel analysis of pericyclic reaction 16th examination |
| Prerequisites |
| The students to take this course are strongly required having studying experience organic chemistry covering terms and area corresponding to those the undergraduate students of Department of Organic and Polymer Materials Chemistry should generally study for period of three years. In addition to class time, prepare and review according to our standard time. |
| Required Text(s) and Materials |
| Not specified. To inform such documents during class hour as necessary. |
| References |
| Not specified. To inform such documents during class hour as necessary. |
| Assessment/Grading |
| Evaluate by the final exam. Depending on the situation, there may be changes based on the fact that there is no disadvantage to students, such as additional evaluation of students who have made meaningful discussions. |
| Message from instructor(s) |
| Non Japanese-native students who are planning to attend the course, please contact the instructor. |
| Course keywords |
| Fundamental and Advanced Organic and Polymer Materials Chemistry, Organic Molecular Materials |
| Office hours |
| Remarks 1 |
| Remarks 2 |
| Related URL |
| Lecture Language |
| Language Subject |
| Last update |
| 3/19/2019 6:51:52 PM |