| Course title | |||||
| 化学結合論 [Theory of Chemical Bonding] | |||||
| Course category | Requirement | Credit | 2 | ||
| Department | Year | 2～ | Semester | 1st | |
| Course type | 1st | Course code | 01en2008 | ||
| Instructor(s) | |||||
| 高栁 正夫 [TAKAYANAGI Masao] | |||||
| Facility affiliation | United Graduate School Agricultural Science | Office | afjgxte/L1151 | Email address | |
| Course description |
|
This course is one of the fundamental subjects (Chemistry) for the department. The purpose of this course is the acquisition of the fundamental knowledge on the constitution of atoms, molecules, and materials based on quantum chemistry in order to understand the structures and behaviors of materials dealt in natural sciences such as environmental science and natural resource science. Intuitive understanding of quantum chemistry with the use of minimum number of formulas is aimed. Firstly, consistent understanding of electronic structures, energies, and properties of atoms based on several simple quantum chemical principles is lectured. Secondly, the mechanism of the formation of chemical bonds between atoms and the varieties of chemical bonds are lectured. The relation between the character of chemical bond and the structure of molecule including the bond is also discussed. Thirdly, intermolecular interaction, which causes the association of molecules to materials and affects their structures and properties, is discussed briefly. |
| Expected Learning |
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(1) Quantum chemical understanding of (i) structures of atoms, (ii) electronic structures of atoms, and (iii) the principles with which properties of atoms are determined by their electronic structure. (2) Quantum chemical understanding of (i) the principle of the formation of chemical bonds, (ii) varieties of chemical bonds, and (iii) the relation between the character of chemical bond and the structure of molecule including the bond. (3) Understanding of intermolecular interaction which works in liquid and solid materials and determines their properties. Corresponding criteria in the Diploma policy: See the curriculum maps. https://www.tuat.ac.jp/campuslife_career/campuslife/policy/ |
| Course schedule |
|
Assuming that students have studied the relevant section of the textbook in advance, I will lecture mainly important points and/or points hard to understand in the textbook with the related matters. Discussion and practice are also held. Lecture No. 1 （April 14）Class on this day will start at around 11:15. Introduction Positioning of this course in the department curriculum The aim and target of this course History of development of chemical bond theory (Textbook Chapter 1) Lectures No. 2 and 3 （April 21 and April 28） Structure of atoms and fundamental quantum chemistry (Textbook Chapter 2) Lectures No. 4 and 5 （May 12 and May 19） Electronic structures in atoms (Textbook Chapter 3) Lecture No. 6 （May 26） Simulation practice 1: Calculations of orbitals in a hydrogen atom Lectures No. 7, 8, and 9 （June 2, June 9 and June 13） Chemical bond of diatomic molecules (Textbook Chapter 4) 45-minutes mid-term examination will be held in Lecture No. 8 or Lecture No. 9. Lectures No. 10 and 11 （June 16 and June 23） Chemical bonds and structures of multi-atomic molecules (Textbook Chapter 5) Lecture No. 12 （Juney 30） Simulation practice 2: Calculations of bonds in a hydrogen molecule Lectures No. 13 and 14 （July 7 and July 14） Metal complexes and coordinate bonds (Textbook Chapter 6) Lectures No. 15 （July 21） Molecular complexes and assemblies (Textbook Chapter 7) Final examination (July 28) |
| Prerequisites |
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Knowledge of chemistry and physics learned at high schools is helpful for understanding of the contents of this lecture. TAT Chemistry has deep relation with this lecture. In addition to 30 hours for attending the course, you should conduct preparations and review by refering to textbooks and distributed lecture materials to satisfy our standard number of hours. |
| Required Text(s) and Materials |
| Gen'etsu MATSUBAYASHI，化学結合の基礎 second edition，三共出版 |
| References |
|
阿武聡信 他「現代物理化学」培?館 中?宗隆「化学結合論」裳華房 中?宗隆「化学－基本の考え?13章 第2版」東京化学同? 中?宗隆「量?化学－基本の考え?16章」東京化学同? |
| Assessment/Grading |
|
Papers on specific subjects (several times) 10% Small tests held in lectures (several times) 10% Mid-term examination 20% Final examination 60% Questions of the final examinations held in the past three years will be distributed around June. Past results （Before 2012, En class and Rn class were combined together. ） 2019 S: 17%, A:32%, B:19%, C:27%, D:5% 2018 S: 11%, A:24%, B:30%, C:30%, D:5% 2017 S: 14%, A:17%, B:35%, C:24%, D:10% 2016 S:16%, A:14%, B:42%, C:25%, D:3% 2015 S:10%, A:22%, B:31%, C:24%, D:13% 2014 S:15%, A:19%, B:24%, C:32%, D:10% 2013 S: 5%, A:27%, B:24%, C:29%, D:15% 2012 S: 8%, A:18%, B:33%, C:28%, D:13% 2011 S:16%, A:20%, B:32%, C:18%, D:14% 2010 S:22%, A:19%, B:23%, C:15%, D:21% 2009 S:17%, A:29%, B:20%, C:13%, D:21% 2008 S: 4%, A:16%, B:25%, C:38%, D:17% 2007 S:14%, A:12%, B:31%, C:26%, D:17% |
| Message from instructor(s) |
| Some Students may be afraid that they have to remember a lot of matters when they study chemistry. To tell the truth, however, the structures and properties of atoms, molecules, and materials are governed by only a few fundamental principles. If you understand the principles and become accustom to seeing the world of materials according to the principles, you need to remember not many matters relating materials any more, and you will find how systematic and beautiful the world of material is. |
| Course keywords |
| Structure of atom, chemical bonds, structure of molecules, structure of materials, quantum chemistry |
| Office hours |
| Tuesday 12:30-14:30. Please make appointment through e-mail prior to meet for the questions and discussions. |
| Remarks 1 |
| Remarks 2 |
| Related URL |
| Lecture Language |
| Japanese |
| Language Subject |
| Last update |
| 12/19/2019 5:03:06 PM |