Course title
有機化学基礎   [Fundamental Organic Chemistry]
Course category	technology speciality courses	Requirement		Credit	2
Department		Year	1～4	Semester	3rd
Course type	3rd	Course code	021411
Instructor(s)
飯島 淳, 大橋 秀伯   [IJIMA Jun, OHASHI Hidenori]
Facility affiliation	Graduate School of Engineering	Office	afjgxte/L1151	Email address

Course description

This course provides students with fundamentals of organic chemistry. After confirming the basis of organic compound, nomenclature, structure, properties, synthesis, reactivity of alkane, haloalkane, alcohol, ether, alkene, alkyne, and aromatic compound are lectured. Also, basic stereochemistry and the reaction mechanism using bent arrow are lectured.

Expected Learning

To acquire the basis of organic chemistry and to understand the synthesis and reactivity from the view point of the properties of functional groups.

Course schedule

#1. Guidance, Structure and bonding of organic compound 　　Coulombic attraction, Bonding, Lewis structure, Resonance structure 　　Atomic orbital and molecular orbital, Hybrid orbital #2. Structure of alkane 　　Nomenclature, Structure and properties, Conformation, Potential energy #3. Reaction of alkane 　　Radical, Hyperconjugation, Radical chain mechanism, Relative reactivity and selectivity #4. Cycloalkane 　　Nomenclature, Properties, Ring strain and structure, cyclohexane and substituted cyclohexane #5. Stereoisomer 　　Chiral molecule, optical activity, R, S nomenclature, Fischer projection, Diastereomer 　　Meso compound, #6. Properties and reaction of haloalkane 　　Nomenclature, Properties, Nucleophilic substitution reaction, Stereochemistry of SN2 reaction 　　Leaving group ability, Nucleophilicity #7. Reaction of haloalkane 　　SN1 reaction, E1 reaction, E2 reaction, Competition of elimination reaction with substitution #8. Midterm Exam (Exam coverage: #1~#7) #9. Hydroxyl group 　　Nomenclature, Synthesis of alcohol, Organometallic reagent #10. Reaction of alcohol and chemistry of ether 　　Synthesis of alkoxide, Substitution and elimination of alcohol, Rearrangement of carbocation #11. Structure of alkene 　　Nomenclature, Structure and properties, Synthesis of alkene #12. Reaction of alkene Electrophilic addition, Markovnikov’s rule, Ozonolysis #13. Structure and reaction of circular sextet electronic system 　　Nomenclature, Structure and resonance energy, Hucklel’s rule, Electrophilic substitution 　　Friedel-Crafts reaction #14. Electrophilic attack to the benzene analogues 　　Activation and inactivation of benzene ring by substituent, Orientation #15. Final examination (Exam coverage: #9~#14)

Prerequisites

「Basic Inorganic Chemistry」in Spring semester wish to be learned.

Required Text(s) and Materials

“Vollhardt ? Schore Organic Chemistry” by K. P. C. Vollhardt, N. E. Schore

References

“McMurry Fundamentals of Organic Chemistry” by J. McMurry “McMurry Organic Chemistry” by J. McMurry “Basic Organic Chemistry” by K. Ohshima “Jones Organic Chemistry” by M. Jones, Jr., S. A. Fleming

Assessment/Grading

Attitude (15%), Mid examination (45%), Final examination (40%)

Message from instructor(s)

Based on the basic inorganic chemistry in Spring semester, basic organic chemistry is lectured.

Course keywords

Alkane, Haloalkane, Hydroxyl compound, Alkene, Alkyne, Aromatic compound

Office hours

I’m (Dr. Iijima) a part-time lecturer, so Q&A is welcomed after each course. Also, before the exam, Q&A using E-mail is acceptable as much as possible.

Remarks 1

Remarks 2

Related URL

Lecture Language

Japanese

Language Subject

Last update

3/16/2021 12:42:52 PM