| Course title | |||||
| 有機金属化学 [Organometallic Chemistry] | |||||
| Course category | technology speciality courses | Requirement | Credit | 2 | |
| Department | Year | 3～4 | Semester | 3rd | |
| Course type | 3rd | Course code | 023365 | ||
| Instructor(s) | |||||
| 平野 雅文 [HIRANO Masafumi] | |||||
| Facility affiliation | Faculty of Engineering | Office | Email address | ||
| Course description |
|
[Class Code for Google Classroom] bruuyi7 [Objective] Reactions using organometallic compounds are essential in modern organic synthesis chemistry, and the recent Nobel Prize in Chemistry has been selected in the field of organometallic chemistry. Organometallic chemistry is a hybrid of organic and inorganic chemistry and is also a frontier. Therefore, a systematic understanding based on knowledge of organic chemistry and inorganic chemistry is desired. The position within the specialized subject is an elementary understanding of chemistry, which is the boundary region between organic chemistry, inorganic chemistry and catalytic chemistry. [Outline] In this lecture, the definition of organometallic compounds, structural features, elementary reactions, basic catalytic reactions and recent catalytic reactions will be taught. Regarding catalytic reactions using organometallic compounds, several examples were given in "Organic Chemistry III", but only examples were introduced. In order to deepen the understanding of the catalytic reaction in this lecture, the lecture will be advanced step by step so that it can be correctly understood that the catalytic reaction is composed of combinations of elementary reactions caused by organometallic compounds. |
| Expected Learning |
|
Understand the nature and elementary reactions of organometallic compounds and understand that catalytic reactions are built by combining elementary reactions. Understand the catalytic reactions of organometallic compounds used in general organic synthetic chemistry. Please refer to the curriculum map in the course guide for the curriculum policy of this course. |
| Course schedule |
|
Organometallic chemistry and molecular catalysis are one of the modern leading fields both in inorganic and organic chemistries. In this class, the fundamental chemistry in these developing fields will be prelected. Lecture 1: opening talk: introduction Lecture 2: what is the organometallic compounds Lecture 3: features of ligands Lecture 4: synthesis of organometallic compounds Lecture 5: basic reactions by organometallic compounds Lecture 6: homogeneous hydrogenation Lecture 7: hydrosilylations/borylation/carbonylation Lecture 8: mid term exam Lecture 9: functionalization of alkenes Lecture 10: allylation reactions Lecture 11: olefin metathesis reactions Lecture 12: cross coupling reactions Lecture 13: catalytic C-H bond activation Lecture 14: recent topics Lecture 15: Comprehensive summary final exam. |
| Prerequisites |
| Organic chemistry I, II, III and IV, inorganic chemistry I and II are taken. Students who have not taken these courses will be allowed to take the course, but the lecture will proceed on the premise that they know the content of the course. For this reason, reviewing these lectures is also important and requires four hours of study every week for preparation, lectures, homework, assignment reports, review, etc. |
| Required Text(s) and Materials |
| Organometallic Chemistry by Fumitoshi Kakiuchi, Kyoritsu Publlishers, ISBN 978-4-320-04411-1. You can download the PowerPoint file used in this course from the Moodle system. However, due to copyright issues, it is only used for personal learning, and reproduction or distribution is prohibited. Assignments and homework will be made through Moodle in a timely manner. |
| References |
| Assessment/Grading |
|
Homework / report /etc 20 points, mid-term exam 40 points, final exam 40 points. 90 points or more S, 80 points to less than 90 points A, 70 points to less than 80 points B , C is 60 points or more and less than 70 points, and D or E is less than 60 points. The distribution of results in fiscal 2018 was S (5%), A (39%), B (24%), C (24%), and D (7%). |
| Message from instructor(s) |
| Organometallic compounds are a treasure trove of new reactions, and are also used as raw materials for electronic materials such as polymer batteries and semiconductors, and are the most advanced academic fields. However, knowledge of both organic chemistry and inorganic chemistry is indispensable for a perfect understanding, and it is difficult to master organometallic compounds without basic knowledge. A good understanding of this area will surely help in the future. |
| Course keywords |
| Organometallic Compounds, Molecular Catalyses |
| Office hours |
| Monday.12:00-13:00. However, you can contact me with email. |
| Remarks 1 |
| As a general rule, the score of the exam will be scored within 24 hours, and the student ID number and score will be posted in the elevator hall on the 5th floor of New Building No. 1 for the next 6 days. If you do not wish to be disclosed, please make a written request before the second lecture. In this case, the inquiry of the score cannot be accepted. |
| Remarks 2 |
| Related URL |
| Lecture Language |
| Japanese |
| Language Subject |
| Last update |
| 1/14/2022 4:31:29 PM |